计算pH=4.0,含有0.1000mol/L的草酸溶液和0.0100mol/LEDTA的溶液中CaC2O4的溶解度(KspCaC2O4=2.0×10-9,lgKCaY=10.69,草酸的解离常数为pKa1sub>=1.23,pKa2=4.19,pH=4.0时lgαY(H)=8.44)
【正确答案】:αCa=1+KcaY[Y]=1+KCaYcY/αY(H)=2.78
α草酸=1+β1[H+]+β2</sub>[H+]2=2.55
Ksp’=KspαCaα草酸=1.42×10-8
S=Ksp’/C草酸=1.42×10-7mol/L